Angelina Jolie, who is now single, has been married three times since 1996. Find out about her ex-husbands here. Angelina Jolie, 46, may get a lot of attention for her acting talents, but... Angelina Jolie, an actress, filmmaker, and humanitarian, has captivated audiences worldwide with her talent and dedication. However, her personal life, particularly her relationships, has often been a subject of intrigue. In the realm of Hollywood, where relationships are often scrutinized, Jolie's journey as a spouse has been both inspiring and tumultuous. As we explore the life of Angelina Jolie's spouse, we delve into the complexities of love, fame, and family that shape her narrative. Angelina Jolie, one of Hollywood’s most beloved and influential actresses, has made headlines not only for her successful career but also for her high-profile relationships. From her marriage to actor Brad Pitt, which ended in one of the most talked-about divorces in recent history, to her humanitarian efforts, Jolie’s life has always been in the public eye. But one of the recurring questions many fans have is: who is Angelina Jolie married to now? As of 2025, the answer is no one. Jolie ... Jolie met Billy Bob Thornton on the set of the 1999 film Pushing Tin, in which they played husband and wife. Both were in other relationships, with Thornton reportedly engaged to actress Laura Dern.