Gattermann-Koch Reaction About Gattermann-Koch Reaction Benzaldehyde and many aromatic aldehydes are conveniently synthesized by treating benzene (or other aromatic compounds) with a mixture of carbon monoxide and hydrogen chloride (compounds of formyl chloride) in the presence of an equimolecular quantity of Lewis acid and a trace of copper (I) chloride. The initially formed cation (C+HO) adds to the benzene nucleus to give the σ complex which yields the aldehyde. Reaction Mechanism of ... Learn about the Gattermann Koch Reaction , its mechanism, required conditions, suitable substrates, and real world applications. A complete guide for chemistry students and aspirants. The Gattermann – Koch reaction is a variant of the Gattermann reaction in which carbon monoxide is used instead of hydrogen cyanide to formylate aromatic compounds. It is named after Ludwig Gattermann and Julius Arnold Koch , and is similar to the Friedel–Crafts reaction . What is Gattermann Koch reaction ? The reaction is named after two German chemists Ludwig Gattermann and Julius Arnold Koch . In the Gattermann Koch reaction , instead of using hydrogen cyanide, we use carbon monoxide. The other names of Gattermann Koch reaction are Gattermann Koch formylation reaction and Gattermann salicylaldehyde synthesis.

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